Volume 6, Issue 2, June 2018, Page: 23-34
Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants
Ibrahim Abdelsalam Sabbah, Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
Mostafa Eid Hendawy, Chemistry Department, Faculty of Science, Al-Azhar University, Cairo, Egypt
Mohammed Fahmy Zaky, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Nabel Abdelmonem Negm, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt
Received: Jun. 12, 2018;       Accepted: Jun. 25, 2018;       Published: Jul. 27, 2018
DOI: 10.11648/j.mc.20180602.13      View  519      Downloads  39
A series of cationic polyurethane surfactant [PQ14, PQ16 and PQ18] were synthesized by the reaction of alkyl bromoacetate (namely: tetradecyl-, hexadecyl- and octadecyl bromoacetate) as quaternizing agents and modified polyurethane contains tertiary amine species. Modified polyurethane was prepared by the reaction of toluene diisocyanate (TDI) and Triethanol amine mono mercaptoacetate. Grinding method is used to synthesize copper and nickel nanoparticles which stabilized by Cationic Thiol polyurethane surfactants. The chemical structures of the prepared surfactants were confirmed using elemental analysis, FTIR, UV and 1H-NMR spectroscopy. The molecular weight measurements of the prepared polymers showed that the segments of each polymer contain average 10 units of the urethane-Triethanol amine mercaptoacetate. The surface activities of the prepared surfactants including: surface tension (g), effectiveness (πcmc), concentration at micelle formation (CMC), efficiency (Pc20), maximum concentration at the interface (Gmax), average area occupied by each surfactant molecule at the interface at equilibrium (Amin) of surfactants solutions were established at 25°C. The surface tension and the critical micelle concentration values of the prepared surfactants were gradually decreased by the gradual increase of their alkyl chain length. Antimicrobial activity of the synthesized cationic surfactants and their nanostructure with copper and nickel nanoparticles were evaluated against pathogenic bacteria and fungi. The antimicrobial activity showed the enhancement in the antimicrobial activity of the synthesized cationic surfactants in the nanostructures form.
Cationic Surfactants, Micellization, Adsorption, Surface Properties, Polyurethane, Antimicrobial Activity
To cite this article
Ibrahim Abdelsalam Sabbah, Mostafa Eid Hendawy, Mohammed Fahmy Zaky, Nabel Abdelmonem Negm, Synthesis, Surface Activities and Anti-Bacterial Activity of (Copper and Nickel) Nanoparticles Stabilized by Cationic Thiol Polyurethane Surfactants, Modern Chemistry. Vol. 6, No. 2, 2018, pp. 23-34. doi: 10.11648/j.mc.20180602.13
Copyright © 2018 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Akita S, Akino K, Imaizumi T, Tanaka K, Anraku K, Yano H, Hirano A, (2006) A polyurethane dressing is beneficial for split-thickness skin-graft donor wound healing. Burns 32:447–451.
Ismail EA, Motawie AM, Sadek EM, (2011) Synthesis and characterization of polyurethane coatings based on soybean oil–polyester polyols Egypt J Petrol 20:1–8.
Mekewi MA, Ramadan AM, El Darse FM, Abdel Rehim MH, Mosa NA, Ibrahim MA (2017) Preparation and characterization of polyurethane plasticizer for flexible packaging applications: Natural oils affirmed access. Egypt J Petrol 26:9–15.
Radhakrishnan B, Cloutet E, Cramail H, (2002) Synthesis of uniform polyurethane particles by step growth polymerization in a dispersed medium, Colloid Polym Sci 280: 1122–1130.
Randall D, Lee S, The Polyurethane Book, Wiley (ISBN: 978-0-470-85041-1) (2003).
Lapprand A, Boisson F, Delolme F, Méchin F, Pascault JP (2005) Reactivity of isocyanates with urethanes: Conditions for allophanate formation, Polym Degrad Stab 90:363-373.
Fisicaro E, Biemmi M, Compari C, Duce E, (2007) Thermodynamic properties of aqueous micellar solutions of some new acetylated gluco-cationic surfactants. Colloids Surf A 301:129–136
Negm NA, Mohamed AS, (2008) Synthesis, characterization and biological activity of sugar-based gemini cationic amphiphiles. J Surfact Deterg 11:215-221.
Shokry SA, El Morsi AK, Sabaa MS, Mohamed RR, El Sorogy HE (2015) Synthesis and characterization of polyurethane based on hydroxyl terminated polybutadiene and reinforced by carbon nanotubes. Egypt J Petrol 24:145–54.
Negm NA, Morsy SMI, (2005) Corrosion inhibition of triethanol ammonium bromide mono-and dibenzoate as cationic inhibitors in an acidic medium. J Surfact Deterg 8:283-287.
Zaki MF, Badawi AM, Sabbah IA, Abdelghani RA, Hendawy ME, (2015) Synthesis, Characterization and Surface Activities of Cationic Polysaccharide (Aloe) Schiff Base Surfactants. J Surfact Deterg 18:455-461.
Negm NA, El Hashash MA, Youssif MA, Ismail EA, Abdeen ZI, Abdel Rahman NR, (2017) Novel Nonionic Polyurethane Surfactants and Ag Nanohybrids: Influence of Nonionic Polymeric Chains. J Surfact Deterg 20:173-182.
Saleh N, Khowdiary M, Badawi AM, (2014), Synthesis and Antitumor and Surface Activity of Novel Tetrachloro Metallate Complexes of Sulfaquinoxaline with Co (II), Cu (II), or Sn (II) Chlorides, Tenside Surf. Det. 51: 4-15.
Sara Busi , Manu Lahtinen, Jussi Valkonen, Kari Rissanen, (2006), Crystal structures and thermal behavior of bis [dibenzyldimethylammonium] CuBr4, bis [dibenzyldimethylammonium] CuCl4 and bis [dimethyldi (2 phenylethyl) ammonium] CuBr4 crystallized from acetonitrile and dilute HX (XZCl or Br) solutions, Journal of Molecular Structure 794: 277–287.
Negm NA, Abd-Elaal AA, Mohamed DE, El-Farargy AF, Mohamed S, (2015) Synthesis and evaluation of silver nanoparticles loaded with Gemini surfactants: surface and antimicrobial activity. J Ind Eng Chem.; 24:34–41.
Azzam EMS, El-Frarrge AFM, Ismail DA, Abd-Elaal AA, (2011) Enhancement of the surface activity for some monomeric and polymeric thiol surfactants using silver nanoparticles. J Disp Sci Technol 32:816–22.
Negm NA, Zaki MF, Salem MAI, (2010) Synthesis and evaluation of 4-diethyl amino benzaldehyde Schiff base cationic amphiphiles as corrosion inhibitors for carbon steel in different acidic media. J Disp Sci Technol 12:321–329.
Hafiz AA, Badawi AM, El-Deeb FI, Soliman EA, El-Awady MY, (2010) Ferrocene-based cationic surfactants: surface and antimicrobial properties. J Surfact Deterg 13:165–172.
Negm NA, El-Farargy AF, Tawfik SM, Abdelnour AM, Hefni HH (2013) Synthesis, surface and thermodynamic properties of substituted poly triethanolamine nonionic surfactants. J Surfact Deterg 16:333-342.
Negm NA, Tawfik SM, Badr EA, Abdou MI, Ghuiba FM, (2015) Evaluation of some nonionic surfactants derived from vanillin as corrosion inhibitors for carbon steel during drilling processes. J Surfact Deterg 18:413-419.
Migahed MA, Negm NA, Shaban MM, Ali TA, Fadda AA, (2016) Synthesis, Characterization, Surface and Biological Activity of Diquaternary Cationic Surfactants Containing Ester Linkage. J Surfact Deterg 19:119-128.
El-Sukkary MMA, Ghuiba FM, Sayed GH, Abdou MI, Badr EA, Tawfik SM, Negm NA, (2014) Evaluation of some vanillin-modified polyoxyethylene surfactants as additives for water based mud. Egypt J Petrol 23:7–14.
Kronberg B, Castas M, Silvestonti R, (1994) Understanding the hydrophobic effect. J Disp Sci Technol 15:333-351.
Kuperkar K, Modi J, Patel K, (2012) Surface-active properties and antimicrobial study of conventional cationic and synthesized symmetrical Gemini surfactants. J Surfact Deterg 15:107–115.
Negm NA, Salem MAI, Badawi AM, Zaki MF, (2003) Synthesis, surface and thermodynamic properties of some novel methyl diethanol ammonium bromide as cationic surfactants. Ain Shams Sci Bull 41:1–13.
Negm NA, Mohamed AA, El-Awady MY, (2004) Influence of structure on the cationic polytriethanol ammonium bromide derivatives. I. Synthesis, surface and thermodynamic properties. Egypt J Chem 47:369–381.
Cukurovali A, Yilmaz I, Gur S, Kazaz C, (2006), Synthesis, antibacterial and antifungal activity of some new thiazolylhydrazone derivatives containing 3-substituted cyclobutane ring. Eur. J. Med. Chem. 41: 201-207.
Negm NA, Morsy SMI, Said MM, (2005), Biocidal activity of some Mannich base cationic derivatives. Bioorg. Med. Chem. 13: 5921-5926.
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