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Ultimate and Elemental Analysis of Some Common Charcoal in Southwestern Nigeria

Received: 10 March 2021    Accepted: 29 March 2021    Published: 16 April 2021
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Abstract

Common charcoals from different wood species were collected, identified and prepared for analysis. Ultimate and elemental analyses were carried out. In this study, identified charcoal were characterized. The result showed that in the ultimate analysis, Carbon, Hydrogen and Oxygen are the major content of the charcoal samples and are of great importance for the heating value. Sulphur and Nitrogen content were resent in low in quantity. XRF was used in the elemental analysis and the following elements were detected (Na, Cr, Ni, Cd, Al, K, Mn, P, Ca, Si, Mg, Ti, Fe) In the charcoal samples, the percentages of Si and Al are high while the percentages of (Cd, Fe, Na, Ti, Ni, Mg, P, K, Cr) were low. Percentage of silicon was between 50% to 65% in Albizia zygia, Milicia excelsa, Terminalia avicennioides, Funtumia elastica, Milletia thonningii and Hevea brsiliensis with Hevea brasiliensis having the highest which suggested high slagging propensity. Anogeissus leiocarpa, Afzelia bipindensis, Vitellia paradoxum, and Burkea africana have high Na/K. The ratio of Ca/ Mg is greater than 2 in all the samples. LOI ranges from 54.56 – 7.88% with a mean of 25.978±22.909%.

Published in Modern Chemistry (Volume 9, Issue 1)
DOI 10.11648/j.mc.20210901.13
Page(s) 13-24
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Charcoal, Analysis, Concentration, Ultimate, Elemental

References
[1] Wang Liang, Øyvind Skreiberg, Sam Van Wesenbeeck, Morten G. Gronli, and Michael Jerry Antal (2016). Experimental Study on Charcoal Production from Woody Biomass. EnergyFuels. DOI: 10.1021/acs.energyfuels.6b01039. 1-43.
[2] Ling, Y.-Y., Zhang, J.-J., Liu, K., Ge, M.-H., Wang, M., and Wang, J.-M. (2017). Geochemistry, geochronology, and tectonic setting of Early Cretaceous volcanic rocks in the northern segment of the Tan-Lu Fault region, northeast China. Journal of Asian Earth Sciences, 144, 303–322. doi: 10.1016/j.jseaes.2016.12.025.
[3] Tolosana-Delgado, R., and McKinley, J. (2016). Exploring the joint compositional variability of major components and trace elements in the Tellus soil geochemistry survey (Northern Ireland). Applied Geochemistry, 75, 263–276.
[4] Weltje, G. J., & Tjallingii, R. (2008). Calibration of XRF core scanners for quantitative geochemical logging of sediment cores: Theory and application. Earth Planet Science Letters, 274 (3–4), 423–438.
[5] Young, K. E., Evans, C. A., Hodges, K. V., Bleacher, J. E., & Graff, T. G. (2016). A review of the handheld X-ray fluorescence spectrometer as a tool for field geologic investigations on Earth and in planetary surface exploration. Applied’-Geochemistry, 72, 77–87. doi: 10.1016/j.apgeochem.2016.07.003.
[6] Löwemark, L., Jakobsson, M., Mörth, M., & Backman, J. (2008). Arctic Ocean Mn contents and sediment color cycles. Polar Research, 27, 105–113.
[7] Sabaou, N., Ait-Salem, H., & Zazoun, R. S. (2009). Chemostratigraphy, tectonic setting, and provenance of the Cambro-Ordovician clastic deposits of the subsurface Algerian Sahara. Journal of African Earth Sciences, 55, 158–174.
[8] Rivera, M. B., Giráldez, M. I., & Fernádez-Caliani, J. C. (2016). Assessing the environmental availability of heavy metals in geochemically contaminated soils of the Sierra de Aracena Natural Park (SW Spain). Is there a health risk? Science of the Total Environment, 560–561, 254–265.
[9] Oyedotun, T. D. T. (2016). Historical mining signatures: Geochemical and mineralogical evaluation of sediments in three coastal-estuarine systems. Journal of Coastal Zone Management, 19, 432. doi: 10.4172/2473-3350.1000432.
[10] Chalmers, G. R. L., & Bustin, M. R. (2017). A multidisciplinary approach in determining the maceral (kerogen type) and mineralogical composition of Upper Cretaceous Eagle Ford Formation: Impact on pore development and pore size distribution. International Journal of Coal Geology, 171, 93–110.
[11] Özkul, C., Çiftçi, E., Tokel, S., & Savaş, M. (2017). Boron as an exploration tool for terrestrial borate deposits: A soil geochemical study in Neogene Emet-Hisarcık basin where the world largest borate deposits occur (Kütahya-western Turkey). Journal of Geochemical Exploration, 173, 31–51.
[12] Fahmi, R.; Bridgwater, A. V.; Donnison, I.; Yates, N.; Jones, J. (2008) The effect of lignin and inorganic species in biomass on pyrolysis oil yields, quality and stability. Fuel, 87, 1230−1240.
[13] Zhou, L.; Jia, Y.; Nguyen, T.-H.; Adesina, A. A.; Liu, Z. (2013). Hydropyrolysis characteristics and kinetics of potassium-impregnated pine wood. Fuel Process. Technol. 116, 149−157.
[14] Ren, Q.; Zhao, C. (2012). NOx and N2O precursors from biomass pyrolysis: Nitrogen transformation from amino acid. Environ. Sci. Technol. 46, 4236−4240.
[15] Raclavska, H.; Corsaro, A.; Juchelkova, D.; Sassmanova, V.; ́Frantík, J. (2015). Effect of temperature on the enrichment and volatility of 18 elements during pyrolysis of biomass, coal, and tires. Fuel Process. Technol. 131, 330−337.
[16] Bernardo, M.; Goncalves, M.; Lapa, N.; Barbosa, R.; Mendes, ̧ B.; Pinto, F. (2012). Characterization of chars produced in the co-pyrolysis of different wastes: decontamination study. J. Hazard. Mater. 207−208, 28−35.
[17] Keown, D. M.; Favas, G.; Hayashi, J.-i.; Li, C.-Z. (2005). Volatilisation of alkali and alkaline earth metallic species during the pyrolysis of biomass: differences between sugar cane bagasse and cane trash. Bioresour. Technol. 96, 1570−1577.
[18] Long, J.; Song, H.; Jun, X.; Sheng, S.; Lun-shi, S.; Kai, X.; Yao, Y. (2012). Release characteristics of alkali and alkaline earth metallic species during biomass pyrolysis and steam gasification process. Bioresour. Technol. 116, 278−284.
[19] Agboola S. A. (1979). An Agricultural Atlas of Nigeria, Oxford University Press, Nigeria. P. 248.
[20] NPC (2006). National Population Commission 2006, Abuja, Nigeria.
[21] Faleyimu, O. I., Agbeja, B. O., and Akinyemi, O. (2010). State of forest regeneration in Southwest Nigeria. African Journal of Agricultural Research. 8 (26): 3381-3383.
[22] Borysiuk P., Ružinská, E., Stępowski, A. and Jenczyk-tołłoczko, I. (2014) Possibility of manufacturing of wooden briquettes with the addition of leaves. In: Annals of Warsaw University of Life Sciences – SGGW. Forestry and Wood Technology. Warsaw. 87: 12-17.
[23] Boruszewski, P., Maminski, M. and Ružinská, E. (eds.) (2012) Raw materials and particleboards – a current status and perspectives. Monograph. Publish. Warsaw University of Life Sciences – SGGW Press, Warsaw, 111 p. ISBN 978-83-7583-389-8.
[24] Ružinská E., Krajewski K. J., Mitterová I., Zachar M. and Toman B. (2014) Assessment of selected hazardous and fire technical characteristics of dendromass intended for wooden pellets preparation. Part I.: Analysis of hazardous substances. Scientific Book: “Advances in Fire, Safety and Security Research 2014”. PTEÚ MV SR, 2014, ročník 1, č. 1. s. 1-10. ISBN 978-80-89051-16-8. ISSN 1339-8490.
[25] Ružinská, E., Wilkowski, J., Mitterová, I. and zachar, M. (2015) The New Progressive Polymeric Materials for the Reduction of VOC in the Woodworking Industry. In: Applied Mechanics and Materials. 711: 214- 217.
[26] Zevenhoven, H., Yrjas, P. and Hupa, M. (2010) Ash –forming Matter and Ash –related Problems. Hand book of Combustion: Solids fuels. 493-531.
[27] Lawrence, A., Kumara, R., Nandakumara, K. and Narayanan. K. 2008. A novel tool for assessing slagging propen-sity of coals in PF boilers. Fuel. 87, 946-950.
[28] Liu, J., Huang, X., Withers, B. R., Blalock, E., Liu, K. and Dickson, R. C. (2013). Reducing sphingolipid synthesis orchestrates global changes to extend yeast lifespan. Aging cell 12 (5): 833-841.
[29] Zevenhoven, M., Lehtovaara, J., Storholm, S., and Hupa, M. (2009) Ash forming matter in peat- the role of iron. Presented at Finnish-Swedish Flame Days, 28-29 January 2009, Naantali, Finland.
[30] Zevenhoven, M. (2001) Ash forming matter in Biomass fuels. Academic Dissertation. Abo Akademi University, Turku Finland. ISBN: 952-12-0813-9.
[31] Vassilev, S. V., Vassileva, C. G., Song, Y-C., Li, W-Y., Feng, J., (2017). Ash contents and Ash forming elements of biomass and their significance for solid biofuel combustion. Fuel. 208: 377-409.
[32] Carvalho, A., Rabaçal, M., Costa, M., Alzueta, M. U., Abián, M. (2017). Effects of potassium and calcium on the early stages of combustion of single biomass particles. Fuel, 209, 787-794.
[33] Choi, M., Scholl, U. I., Yue, P., Bjorklund, P., Zhao, B., Nelson-Williams, C., Ji, W., Cho, Y., Pael, A., and Men, C. J. (2011) K+ channel mutations in adrenal aldosterone-producing adenomas and hereditary hypertension. Science, 331, 768–772.
[34] Durie, R. (2013) The science of Victorian brown coal: structure, properties and consequences for utilization: Butterworth-Heinemann, 2013. Available: https://www.bookdepository.com/Science-Victorian-Brown-Coal-R-Durie/9780750604208.
[35] Werkelin, J. (2008) Ash Forming Matter and their Chemical Forms in Woody Biomass Fuels, PhD thesis, Abo Akademi University.
[36] Liu, W-J., Li, W-W., Jiang, H., and Yu, H-Q (2017) Fates of Chemical Elements in Biomass during its Prolysis. CAS Key. Laboratory of Urban Pollutant Conversion. American Chemical Society. 117: 6367-6398.
[37] Vopršalová, M. and Záčková, P. (2000) Základy toxikologie pro farmaceuty. Toxicology bases for pharmacists.. Charles Univerzity, Praha. Publishing house UK Karolinium,. pp. 233 ISBN 80-7184-282-6.
[38] Bhavani, P. and Sujatha, B. (2014) Impact of Toxic metals leading to environmental Pollution. Journal of Chemical and Pharmaceutical Sciences. 70-72.
[39] Beiglbock, C., Steineck, T., Tataruch, F., and Ruf, T. (2001). Environmental cadmium induces histopathological changes in Kidney of roe deer. Environ. Toxicol. Chem.. 12: 1811-1816.
[40] WHO (2003). World Health Survey. Geneva. The World Health Organization.
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  • APA Style

    Jacob Ademola Sonibare, Michael Abidemi Oke, Onakpohor Anthony, Akeredolu Funsho Akeredolu. (2021). Ultimate and Elemental Analysis of Some Common Charcoal in Southwestern Nigeria. Modern Chemistry, 9(1), 13-24. https://doi.org/10.11648/j.mc.20210901.13

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    ACS Style

    Jacob Ademola Sonibare; Michael Abidemi Oke; Onakpohor Anthony; Akeredolu Funsho Akeredolu. Ultimate and Elemental Analysis of Some Common Charcoal in Southwestern Nigeria. Mod. Chem. 2021, 9(1), 13-24. doi: 10.11648/j.mc.20210901.13

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    AMA Style

    Jacob Ademola Sonibare, Michael Abidemi Oke, Onakpohor Anthony, Akeredolu Funsho Akeredolu. Ultimate and Elemental Analysis of Some Common Charcoal in Southwestern Nigeria. Mod Chem. 2021;9(1):13-24. doi: 10.11648/j.mc.20210901.13

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  • @article{10.11648/j.mc.20210901.13,
      author = {Jacob Ademola Sonibare and Michael Abidemi Oke and Onakpohor Anthony and Akeredolu Funsho Akeredolu},
      title = {Ultimate and Elemental Analysis of Some Common Charcoal in Southwestern Nigeria},
      journal = {Modern Chemistry},
      volume = {9},
      number = {1},
      pages = {13-24},
      doi = {10.11648/j.mc.20210901.13},
      url = {https://doi.org/10.11648/j.mc.20210901.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20210901.13},
      abstract = {Common charcoals from different wood species were collected, identified and prepared for analysis. Ultimate and elemental analyses were carried out. In this study, identified charcoal were characterized. The result showed that in the ultimate analysis, Carbon, Hydrogen and Oxygen are the major content of the charcoal samples and are of great importance for the heating value. Sulphur and Nitrogen content were resent in low in quantity. XRF was used in the elemental analysis and the following elements were detected (Na, Cr, Ni, Cd, Al, K, Mn, P, Ca, Si, Mg, Ti, Fe) In the charcoal samples, the percentages of Si and Al are high while the percentages of (Cd, Fe, Na, Ti, Ni, Mg, P, K, Cr) were low. Percentage of silicon was between 50% to 65% in Albizia zygia, Milicia excelsa, Terminalia avicennioides, Funtumia elastica, Milletia thonningii and Hevea brsiliensis with Hevea brasiliensis having the highest which suggested high slagging propensity. Anogeissus leiocarpa, Afzelia bipindensis, Vitellia paradoxum, and Burkea africana have high Na/K. The ratio of Ca/ Mg is greater than 2 in all the samples. LOI ranges from 54.56 – 7.88% with a mean of 25.978±22.909%.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Ultimate and Elemental Analysis of Some Common Charcoal in Southwestern Nigeria
    AU  - Jacob Ademola Sonibare
    AU  - Michael Abidemi Oke
    AU  - Onakpohor Anthony
    AU  - Akeredolu Funsho Akeredolu
    Y1  - 2021/04/16
    PY  - 2021
    N1  - https://doi.org/10.11648/j.mc.20210901.13
    DO  - 10.11648/j.mc.20210901.13
    T2  - Modern Chemistry
    JF  - Modern Chemistry
    JO  - Modern Chemistry
    SP  - 13
    EP  - 24
    PB  - Science Publishing Group
    SN  - 2329-180X
    UR  - https://doi.org/10.11648/j.mc.20210901.13
    AB  - Common charcoals from different wood species were collected, identified and prepared for analysis. Ultimate and elemental analyses were carried out. In this study, identified charcoal were characterized. The result showed that in the ultimate analysis, Carbon, Hydrogen and Oxygen are the major content of the charcoal samples and are of great importance for the heating value. Sulphur and Nitrogen content were resent in low in quantity. XRF was used in the elemental analysis and the following elements were detected (Na, Cr, Ni, Cd, Al, K, Mn, P, Ca, Si, Mg, Ti, Fe) In the charcoal samples, the percentages of Si and Al are high while the percentages of (Cd, Fe, Na, Ti, Ni, Mg, P, K, Cr) were low. Percentage of silicon was between 50% to 65% in Albizia zygia, Milicia excelsa, Terminalia avicennioides, Funtumia elastica, Milletia thonningii and Hevea brsiliensis with Hevea brasiliensis having the highest which suggested high slagging propensity. Anogeissus leiocarpa, Afzelia bipindensis, Vitellia paradoxum, and Burkea africana have high Na/K. The ratio of Ca/ Mg is greater than 2 in all the samples. LOI ranges from 54.56 – 7.88% with a mean of 25.978±22.909%.
    VL  - 9
    IS  - 1
    ER  - 

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Author Information
  • Environmental Engineering Research Laboratory, Department of Chemical Engineering, Obafemi Awolowo University, Ile-Ife, Nigeria

  • Environmental Engineering Research Laboratory, Department of Chemical Engineering, Obafemi Awolowo University, Ile-Ife, Nigeria

  • Environmental Engineering Research Laboratory, Department of Chemical Engineering, Obafemi Awolowo University, Ile-Ife, Nigeria

  • Environmental Engineering Research Laboratory, Department of Chemical Engineering, Obafemi Awolowo University, Ile-Ife, Nigeria

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